Amine induced carbonylation of alkynes to cyclobutenediones using Fe3(CO)12

Rameshkumar, Chellappan ; Periasamy, Mariappan (2000) Amine induced carbonylation of alkynes to cyclobutenediones using Fe3(CO)12 Tetrahedron Letters, 41 (15). 2719-2722 . ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(00)00247-1

Abstract

Iron carbonyl species, prepared in situ in THF using Fe3(CO)12, react with alkynes at 25°C, in the presence of certain amines, to give the corresponding cyclobutenediones in moderate to good yields (25–61%) after CuCl2·2H2O oxidation.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Alkynes; Amines; Carbonylation; Cyclobutenediones
ID Code:37134
Deposited On:25 Apr 2011 08:06
Last Modified:25 Apr 2011 08:06

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