Periasamy, Mariappan ; Rameshkumar, Chellappan ; Mukkanti, Amere (2002) Conversion of alkynes to cyclic imides and anhydrides using reactive iron carbonyls prepared from Fe(CO)5 and Fe3(CO)12 Journal of Organometallic Chemistry, 649 (2). 209-213 . ISSN 0022-328X
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00223...
Related URL: http://dx.doi.org/10.1016/S0022-328X(02)01129-4
Abstract
Alkyne-iron carbonyl complexes, prepared using Fe(CO)5–NaBH4–CH3COOH-amine-alkyne and Fe3(CO)12–amine–alkyne reagent systems, react with excess of amine at 25°C to give cyclic imides in moderate to good yields. Further, unsaturated iron carbonyl species, prepared using the Fe(CO)5–pyridine-N-oxide system, react with alkynes to give the corresponding anhydrides.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Alkynes; Iron Carbonyl Complexes; Double Carbonylation; Cyclic Imides |
| ID Code: | 37133 |
| Deposited On: | 25 Apr 2011 08:07 |
| Last Modified: | 25 Apr 2011 08:07 |
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