Lithium tetrafluoborate catalyzed Ferrier Rearrangement - facile synthesis of alkyl 2,3-unsaturated glycopyranosides

Sobhana Babu, B. ; Balasubramanian, K. K. (1999) Lithium tetrafluoborate catalyzed Ferrier Rearrangement - facile synthesis of alkyl 2,3-unsaturated glycopyranosides Synthetic Communications, 29 (24). pp. 4299-4305. ISSN 0039-7911

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Related URL: http://dx.doi.org/10.1080/00397919908086589

Abstract

Treatment of tri-O acetyl-D-galactal 1 and tri-O-acetyl-D-glucal 2 with diverse alcohols in the presence of LiBF4 in CH3CN, furnished alkyl 2,3-unsaturated glycopyranosides 3-18 (50-86%).

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Deposited On:18 Oct 2010 10:01
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