ESR study of coupled pairs of molecules in copper diethyldithiocarbamate

Cowsik, R. K. ; Rangarajan, G. ; Srinivasan, R. (1971) ESR study of coupled pairs of molecules in copper diethyldithiocarbamate Chemical Physics Letters, 8 (1). pp. 137-138. ISSN 0009-2614

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...

Related URL: http://dx.doi.org/10.1016/0009-2614(71)80597-3

Abstract

Single crystal ESR study of copper diethyldithiocarbamate has shown evidence for the presence of coupled pairs of Cu++ ions. While the g-values for the triplet state remain the same as for the doublet (uncoupled ions), the hyperfine splitting is halved. The zero field splitting parameter D=276×10-4 cm-1. The results have been correlated with crystal structure and susceptibility data.

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Deposited On:11 Apr 2011 13:31
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