A reinvestigation of the claisen rearrangement of methyl γ-aryloxycrotonates a convenient synthesis of 3-ethylidenebenzofuran-2(3H)-ones

Sunitha, K. ; Balasubramanian, K. K. (1987) A reinvestigation of the claisen rearrangement of methyl γ-aryloxycrotonates a convenient synthesis of 3-ethylidenebenzofuran-2(3H)-ones Tetrahedron, 43 (14). pp. 3269-3278. ISSN 0040-4020

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4020(01)90295-9

Abstract

The synthesis and Claisen rearrangement of methyl γ-aryloxycrotonates have been reinvestigated. A number of methyl γ-aryloxycrotonates have been prepared and sucessfully rearranged to a mixture of Z and E 3-ethylidenebenzofuran-2(3H)ones in refluxing ethylene glycol.

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