N,N,-dimethyl(chlorosulphenyl)methaniminium chloride mediated direct and chemoselective conversion of carboxylic acids to aldehydes

Khan, R. H. ; Prasada Rao, T. S. R. (1998) N,N,-dimethyl(chlorosulphenyl)methaniminium chloride mediated direct and chemoselective conversion of carboxylic acids to aldehydes Journal of Molecular Catalysis A: Chemical, 135 (1). pp. 111-114. ISSN 1381-1169

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S13811...

Related URL: http://dx.doi.org/10.1016/S1381-1169(98)00164-2

Abstract

A new method for the direct conversion of carboxylic acids to aldehydes using N,N-dimethyl(chlorosulphenyl)methaniminium chloride and lithium triethyl-borohydride (super-hydride) was established. This method provides a convenient way for the chemoselective reduction of carboxylic acids even with such a functional group as halide, ester, nitrile, olefin and ketone.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Carboxylic Acid; Aldehyde; N,N-Dimethyl(chlorosulphenyl)methaniminium Chloride
ID Code:36309
Deposited On:19 Apr 2011 08:00
Last Modified:19 Apr 2011 09:51

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