(Chlorosulfinyloxy)-N,N-dimethylmethaniminium chloride mediated direct and chemoselective conversion of carboxylic acids into aldehydes

Khan, R. H. ; Prasada Rao, T. S. R. (1998) (Chlorosulfinyloxy)-N,N-dimethylmethaniminium chloride mediated direct and chemoselective conversion of carboxylic acids into aldehydes Journal of Chemical Research, Synopses, 1998 (7). pp. 402-403. ISSN 0308-2342

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1998...

Related URL: http://dx.doi.org/10.1039/A709037D

Abstract

A new method for the direct conversion of carboxylic acids into aldehydes using (chlorosulfinyloxy)N,N-dimethylmethaniminium chloride and lithium triethylhydroborate (super-hydride) was established which provides a convenient way for the chemoselective reduction of carboxylic acids even with such functional groups as halide, ester, nitrile, olefin and ketone.

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