Shankar, J. ; de Souza, B. C. (1962) Isotopic exchange in the cobaltous-cobaltic system in perchloric acid Journal of Inorganic and Nuclear Chemistry, 24 (2). pp. 187-193. ISSN 0022-1902
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00221...
Related URL: http://dx.doi.org/10.1016/S0022-1902(62)90294-4
Abstract
Systematic investigations are reported on the isotopic exchange in the cobaltous-cobaltic system using cobalt-60. Ammonia and ethylenediamine were found to be satisfactory quenchers of this fast exchange, even though some zero-time exchange was observed. In the concentration range studied the reaction was found to be of the first order with respect to each reactant. At a high fixed ionic strength (3·1), variation of perchloric acid concentration from 0·25 F to 0·7 F showed an inverse first-order dependence. Possible mechanisms for the exchange are discussed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 35698 |
| Deposited On: | 11 Apr 2011 13:27 |
| Last Modified: | 25 Jun 2012 15:17 |
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