Choudhury, N. Roy ; Ahluwalia, J. C. (1982) Enthalpies and heat capacities of transfer of sodium carboxylates and sodium dodecylsulfate from water to aqueous tert-butyl alcohol solutions Journal of Solution Chemistry, 11 (3). 0095-9782. ISSN 0095-9782
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Official URL: http://www.springerlink.com/content/l363164g3r2366...
Related URL: http://dx.doi.org/10.1007/BF00667601
Abstract
Integral enthalpies of solution at very low concentrations of sodium carboxylates and sodium dodecylsulfate in aqueous tert-butyl alcohol solutions at 25°C and 35°C were measured with an isoperibol submarine calorimeter. The enthalpies and heat capacities of transfer of these surfactants from water to aqueous tertbutyl alcohol solutions were derived from integral enthalpies of solution. The results are explained in terms of the structural alteration effect of the constituent hydrophobic and hydrophilic groups of the solute.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Springer-Verlag. |
| Keywords: | Enthalpies of Transfer; Heat Capacities of Transfer; Sodium Carboxylates; Sodium Dodecylsulfate; Tert-butyl Alcohol-water Mixed Solvent; Hydrophobic and Hydrophilic Effects |
| ID Code: | 337 |
| Deposited On: | 21 Sep 2010 04:48 |
| Last Modified: | 11 May 2011 07:20 |
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