A new 2Π-X2Π band system of NS

Narasimham, N. A. ; Srikameswaran, K. (1964) A new 2Π-X2Π band system of NS Proceedings of the Indian Academy of Sciences, Section A, 59 (4). pp. 227-240. ISSN 0370-0089

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Official URL: http://www.ias.ac.in/j_archive/proca/59/vol59conte...

Related URL: http://dx.doi.org/10.1007/BF03046437


Vibrational and rotational analysis of some bands forming a new band system of NS is given. It is also shown that the system involves the ground X2Π reg. state of the molecule, and is due to the transition 2 Πreg.→X2Πreg. The bands form a single v"=0 progression with v'=7, 8, 9 and 10. The assignment of these quantum numbers v', v" is supported by (1) Δ2F" (J) values which are identical with those for the v"=0 bands of the β and γ systems and (2) the isotopic shift data from 15NS bands, respectively.

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