A new 2π–X2π band system of nitrogen sulphide

Narasimham, N. A. ; Srikameswran, K. (1963) A new 2π–X2π band system of nitrogen sulphide Nature, 197 (4865). p. 370. ISSN 0028-0836

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Official URL: http://www.nature.com/nature/journal/v197/n4865/ab...

Related URL: http://dx.doi.org/10.1038/197370a0


The spectrum of nitrogen sulphide is excited by means of a micro-wave oscillator of 2,450 Mc/s in sealed quartz discharge tubes containing a few mm of nitrogen and traces of sulphur. Besides the β- and γ-bands, a number of hitherto unassigned bands, degraded to the red, are recorded in the region 2650–2850 Å. These are photographed on a 6.6-m concave grating spectrograph in the second order at a dispersion of 0.57 Å/mm. Rotational structure of seven bands has been analysed and the results are reported in the present communication.

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