Terpenoids-LXXXIII: structure of β-bergamotene

Kulkarni, K. S. ; Paknikar, S. K. ; Bhattacharyya, S. C. (1966) Terpenoids-LXXXIII: structure of β-bergamotene Tetrahedron, 22 (6). pp. 1917-1927. ISSN 0040-4020

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4020(01)82265-1


β-Bergamotene, in Indian valerian root oil, is a sesquiterpene analogue of β-pinene. Its structure has been established as I by application of physical methods and chemical degradations to known compounds, pinane (XXIX) and bicycloekasantalic lactone (XXXIII). The possible biogenesis of β-bergamotene and its relationship to other sesquiterpenes, such as α- and β-santalenes has been discussed and conclusions drawn regarding its stereochemistry by comparison of the NMR spectra of these related products.

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