Linkage isomerism in nickel(II) β-isonitroso-imine ligand complexes

Iyengar, R. R. ; Bose, K. S. ; Patel, C. C. (1975) Linkage isomerism in nickel(II) β-isonitroso-imine ligand complexes Journal of Inorganic and Nuclear Chemistry, 37 (1). pp. 75-78. ISSN 0022-1902

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β-isonitroso-imine ligand complexes of nickel(II), namely, bis(isonitrosomethylacetoacetate-imino)Ni(II), Ni(IMI)(IMI'); bis(isonitrosobenzoylacetoneimino)Ni(II), Ni(IBI)(IBI') and bis(isonitrosoacetoacetanilideimino)Ni(II), Ni(IANI)(IANI'), have been prepared and characterized. On the basis of their spectroscopic and magnetic properties, these complexes are suggested to have a square-planar stereochemistry around the metal ion with both nitrogen (ligand denoted without prime) and oxygen (ligand denoted with prime) coordinated isonitroso groups. The i.r. and NMR spectra of these and other similar complexes are discussed.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:33240
Deposited On:30 Mar 2011 13:23
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