Miscibility of poly(phenyl acrylate) with acrylonitrile/styrene copolymers

Sankarapandian, M. ; Kishore, K. (1991) Miscibility of poly(phenyl acrylate) with acrylonitrile/styrene copolymers Macromolecules, 24 (11). pp. 3090-3092. ISSN 0024-9297

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ma00011a010

Related URL: http://dx.doi.org/10.1021/ma00011a010

Abstract

The Blase transition and phase behavior of blends of poly(pheny1 acrylate) with poly(acrylonitri1eco-styrene) was studied by differential scanning calorimetry. It was found that poly(pheny1 acrylate) is miscible with poly(acrylonitri1e-co-styrenes) within a specific range of copolymer composition. The segmental interaction parameters were estimated and found to be positive for all three pairs. The miscibility in thissystem appears to be the consequence of the intramolecular repulsion between styrene and acrylonitrile units.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:31991
Deposited On:19 Mar 2011 11:13
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