Jayaseharan, J. ; Kishore, K. (1998) Biomimetic aerobic polymerization of vinyl monomers Journal of the American Chemical Society, 120 (4). pp. 825-826. ISSN 0002-7863
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ja971335s
Related URL: http://dx.doi.org/10.1021/ja971335s
Abstract
This is the first report of biomimetic aerobic polymerization of vinyl monomers, which has been achieved under mild conditions. When a homogeneous solution of a vinyl monomer containing a reversible oxygen carrier, namely 5,10,15,20 tetraphenyl-21H, 23H-porphinecobalt(II) pyridine complex [CoTPP(Py)], is exposed to air at room temperature, an alternating copolyperoxide is obtained (eq 1).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 31695 |
| Deposited On: | 19 Mar 2011 12:25 |
| Last Modified: | 10 Jun 2011 06:11 |
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