2-Thienylmethylenemalononitrile, C8H4N2S

Mukherjee, A. K. ; Mukherjee (Nee Mondal), M. ; De, Asish ; Bhattacharyya, S. P. (1984) 2-Thienylmethylenemalononitrile, C8H4N2S Acta Crystallographica Section C, 40 (6). pp. 991-992. ISSN 0108-2701

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Official URL: http://onlinelibrary.wiley.com/doi/10.1107/S010827...

Related URL: http://dx.doi.org/10.1107/S0108270184006533

Abstract

Mr =160.2, monoclinic, P21/c, a=5.701 (2), b= 18.613(4). c = 7.473 (3) Å, β= 97.57(3)°, V=786.0Å3, Z = 4, Dx= l.35gcm-3, MoKα, λ-0.7107 Å, μ-3.31 cm-1, F(OO0) = 328, room temperature, R=0.050 for 929 reflections with |Fα| > 4σ(|Fα|). The two planar parts in the molecule, the thiophene ring and the dicyanovinyl moiety, are inclined at 3.6(5)D to one another and the vinylic H atom is trans with respect to the S atom. The electron-withdrawing properties of the cyanide groups affect two of the C-C bond lengths.

Item Type:Article
Source:Copyright of this article belongs to International Union of Crystallography.
ID Code:3103
Deposited On:09 Oct 2010 09:50
Last Modified:23 May 2011 04:22

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