Murugavel, Ramaswamy ; Kumar, Parimal ; Walawalkar, Mrinalini G. ; Mathialagan, Ramyaa (2007) A double helix is the repeating unit in a luminescent calcium 5-aminoisophthalate supramolecular edifice with water-filled hexagonal channels Inorganic Chemistry, 46 (17). pp. 6828-6830. ISSN 0020-1669
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic070113k
Related URL: http://dx.doi.org/10.1021/ic070113k
Abstract
Calcium 5-aminoisophthalate {[Ca(AIP)(OH2)4](H2O)} (1), synthesized from Ca(OH)2 and H2AIP, exists as a double helix. Hydrogen-bonding interactions between metal-bound water molecules, carboxylate oxygen, and the -NH2 group result in the formation of a supramolecular assembly, where the double helices are connected to each other to form hexagonal channels filled with water molecules.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 30416 |
| Deposited On: | 23 Dec 2010 03:05 |
| Last Modified: | 23 Dec 2010 03:05 |
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