Murugavel, Ramaswamy ; Chandrasekhar, Vadapalli (1999) Monovalent group 13 organometallic compounds: weak association to monomeric, versatile two-electron donors Angewandte Chemie International Edition, 38 (9). pp. 1211-1215. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/(SICI)1...
Related URL: http://dx.doi.org/10.1002/(SICI)1521-3773(19990503)38:9<1211::AID-ANIE1211>3.0.CO;2-O
Abstract
A weakly associated hexamer is formed for [GaCp∗ ] (Cp∗=C5Me5) in the solid state (see picture). The recent X-ray crystal structure analyses of [GaCp∗] as well as the monomeric In| and Tl| compounds [M(2,4,6-Trip3C6H2)] (Trip=2,4,6-iPr3C6H2) throw new light on the association and aggregation of monovalent Group 13 elements in the solid state. The synthesis of [Ni0{In[C(SiMe3)3]}4], a complex with terminally bonded In|R ligands, offers alternative σ-donor/π-acceptor ligands to organometallic chemists. The newest results in this area are likely to open up new and intriguing possibilities in the preparation of main group-transition metal clusters.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| Keywords: | Cluster Compounds; Main Group Elements; Metal-metal Interactions; Organometallic Compounds; Subvalent Compounds |
| ID Code: | 30405 |
| Deposited On: | 23 Dec 2010 03:08 |
| Last Modified: | 05 Mar 2011 12:04 |
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