Palanisami, Nallasamy ; Prabusankar, Ganesan ; Murugavel, Ramaswamy (2006) A novel dimeric copper salicylate with an undissociated COOH group: synthesis and crystal structure of [Cu2(HSal)(Sal)(2,2'-bpy)2](ClO4) Inorganic Chemistry Communications, 9 (10). pp. 1002-1006. ISSN 1387-7003
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S13877...
Related URL: http://dx.doi.org/10.1016/j.inoche.2006.05.025
Abstract
A dinuclear copper salicylate [Cu2(HSal)(Sal)(2,2'-bpy)2](ClO4) (1) (H2Sal = salicylic acid) has been synthesized and characterized with the aid of elemental analysis and infrared, ultraviolet and fluorescence spectroscopic studies. The molecular structure of 1, determined by single-crystal X-ray diffraction studies, shows the presence of incompletely deprotonated salicylate ligands in the complex. Hydrogen bonding interactions and π-π aromatic stacking lead to the formation of 2D polymeric structure in the solid state.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Copper Salicylate; Hydrogen Bonding; Crystal Structure |
| ID Code: | 30403 |
| Deposited On: | 23 Dec 2010 03:09 |
| Last Modified: | 03 Mar 2011 07:14 |
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