Voigt, Andreas ; Murugavel, Ramaswamy ; Ritter, Uwe ; Roesky, Herbert W. (1996) Infrared and 29Si NMR spectroscopic investigations on metallasiloxanes derived from organosilanetriols Journal of Organometallic Chemistry, 521 (1-2). pp. 279-286. ISSN 0022-328X
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002232...
Related URL: http://dx.doi.org/10.1016/0022-328X(96)06319-X
Abstract
Silanols containing one or more Si---OH groups are useful synthons for the preparation of metallasiloxanes with novel Si---O---M frameworks. Recent reports from our laboratory in this area were centred on the synthesis of stable organosilanetriols and their use as building-blocks for the preparation of a wide range of metallasiloxanes soluble in organic solvents and incorporating various transition metals and main group elements in the siloxane framework. In addition to single crystal X-ray structural investigations, infrared and 29Si NMR spectral techniques provide useful information for elucidating the structures and type of metallasiloxanes formed in these reactions. This article summarizes the results of studies of the IR and 29Si NMR spectra of these compounds.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Silicon; 29Si NMR Spectra; IR Spectra; Silanetriols; Metallasiloxanes; Group 14 |
| ID Code: | 30400 |
| Deposited On: | 23 Dec 2010 03:09 |
| Last Modified: | 03 Mar 2011 10:15 |
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