Heterobimetallic diethanolaminate complexes of titanium and zirconium with alkaline earth metals

Sharma, Kanupriya ; Sharma, Malti ; Singh, Anirudh ; Mehrotra, Ram C. (2002) Heterobimetallic diethanolaminate complexes of titanium and zirconium with alkaline earth metals Transition Metal Chemistry, 27 (3). pp. 326-328. ISSN 0340-4285

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Official URL: http://www.springerlink.com/content/9w8efb66egmamg...

Related URL: http://dx.doi.org/10.1023/A:1014850808115

Abstract

Ti(OPr i)4 or Zr(OPr i)4·Pr i OH react with hydrocarbon-insoluble complexes M{(OCH2CH2)NH(CH2CH2OH)}2 (M = Mg, Ca, Sr, Ba) in a 2:1 molar ratio to yield hydrocarbon-soluble heterobimetallic diethanolaminate isopropoxide complexes [M{(OCH2CH2)2NH}2{M(OPr i )3}2] (M = Mg, Ca, Sr, Ba; M = Ti, Zr), which have been characterized by elemental analyses, molecular weight measurements and spectroscopic [i.r., n.m.r. (1H and 13C)] studies.

Item Type:Article
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ID Code:30298
Deposited On:22 Dec 2010 09:56
Last Modified:07 Jun 2011 04:33

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