Bhargava, Sanieev ; Bohra, Rakesh ; Mehrotra, Ram C. (1991) Mixed ligand titanium(IV) complexes. Chlorobis(dithiocarbamato)bis(methylsalicylato)titanium(IV) andbis(dithiocarbamato)bis(methylsalicylato)titanium(IV) Transition Metal Chemistry, 16 (2). pp. 622-625. ISSN 0340-4285
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Official URL: http://www.springerlink.com/content/h318556227r482...
Related URL: http://dx.doi.org/10.1007/BF01024201
Abstract
Dichlorobis(methylsalicylato)titanium(IV) reacts with potassium or amine salts of dialkyl or diaryl dithiocarbamates in 11 and 12 molar ratios in anhydrous benzene (room temperature) or in boiling CH2Cl2 to yield mixed ligand complexes: (AcOC6H4O)2 Ti(S2CNR2)Cl (1) and (AcOC6H4O)2 Ti(S2CNR2)2 (2), R=Et, n-Pr, n-Bu, cyclo-C4H8 and cyclo-C5H10. These compounds are moisture sensitive and highly soluble in polar solvents. Molecular weight measurement in conjunction with i.r.,1H and 13C n.m.r. spectral studies suggest coordination number 7 and 8 around titanium(IV) in (1) and (2) respectively.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Springer-Verlag. |
| ID Code: | 30290 |
| Deposited On: | 22 Dec 2010 09:58 |
| Last Modified: | 07 Jun 2011 04:53 |
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