Synthesis, properties and characterization of some mixed ligand complexes of tin(IV). 1. Alkylxanthato(chloro)bis(β-diketonato)tin(IV)

Sharma, Suman ; Bohra, Rakesh ; Mehrotra, Ram C. (1992) Synthesis, properties and characterization of some mixed ligand complexes of tin(IV). 1. Alkylxanthato(chloro)bis(β-diketonato)tin(IV) Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 22 (1). pp. 43-56. ISSN 1553-3174

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Related URL: http://dx.doi.org/10.1080/15533179208020638

Abstract

A few mixed ligand complexes of the type XX'SnL2 (where X =C1, X' = S2COCH3, S2COC3 H7-i, S2COC4H9-n, HL = acetylacetone, benzoylacetone and dibenzoylmethane) have been prepared by the reaction of dlchlorobis-(β -diketonato) tin(IV) with sodium alkylxanthate in acetone under refluxing conditions. The new compounds, characterized by elemental analyses, molecular weight measurements, IR and NMR (1H, 13C, 119Sn) spectral studies, probably have a distorted octahedral geometry and contain monodentate xanthates.

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