Dialkyl dithiophosphates of tantalum(V)

Pandey, Sushil K. ; Srivastava, Ghanshyam ; Mehrotra, Ram C. (1991) Dialkyl dithiophosphates of tantalum(V) Phosphorus, Sulfur, and Silicon and the Related Elements, 61 (1-2). pp. 49-56. ISSN 1042-6507

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Related URL: http://dx.doi.org/10.1080/10426509108027336


Reactions of tantalum(V) isopropoxide with O,O'-dialkyldithiophosphoric acids in equimolar ratio yield tetraisopropoxy tantalum(V) dialkyl dithiophosphates, (PriO)4Ta[S2P(OR)2] (where R = Et, Prn, Pri, Bni, and C6H5) as hydrolysable, yellow viscous liquids, soluble in common organic solvents and monomeric in freezing benzene. These have been characterized by molecular weight determinations and spectral studies like IR and NMR (1H, 13C and 31P). Octahedral structures with chelating bidentate dithiophosphate moieties are suggested for these complexes.

Item Type:Article
Source:Copyright of this article belongs to Taylor and Francis Ltd.
Keywords:Dialkyl Dithiophosphates; Phosphoric Acids; Tantalum(V) Isopropoxide; Tetraisoprop-oxytantalum(V) Dialkyl Dithiophosphates
ID Code:30274
Deposited On:22 Dec 2010 10:28
Last Modified:07 Jun 2011 04:49

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