Synthesis and characterization of heterobimetallic alkoxide triethanolaminate derivatives of zirconium

Sharma, Maneesh K. ; Singh, Anirudh ; Mehrotra, Ram C. (2001) Synthesis and characterization of heterobimetallic alkoxide triethanolaminate derivatives of zirconium Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 31 (3). pp. 371-379. ISSN 1553-3174

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Related URL: http://dx.doi.org/10.1081/SIM-100002225

Abstract

Novel heterobimetallic isopropoxide derivatives have been prepared by the 1:2 molar reactions of Zr(OCH2CH2)2 N(CH2CH2OH)2 with Al(OPr-i)3 or Nb(OPr-i)5 in benzene under refluxing conditions. The reactions of heterobimetallic alkoxide-triethanolaminate derivatives with chelating ligands such as acetylacetone or methoxyethanol have been investigated. All of these derivatives have been characterized by elemental analyses, molecular weight measurements and spectroscopic [IR, NMR (1H, 27Al)] studies.

Item Type:Article
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Deposited On:22 Dec 2010 10:29
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