Oximates and diethylhydroxylaminates of As(III)

Mehrotra, R. C. ; Rai, A. K. ; Bohra, Rakesh (1974) Oximates and diethylhydroxylaminates of As(III) Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 4 (2). pp. 167-177. ISSN 1553-3174

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Related URL: http://dx.doi.org/10.1080/00945717408069647


Mono-, di- and tri-oximates and diethylhydroxylaminates of arsenic have been prepared by the reaction of triethoxy arsine with oximes and diethylhydroxylamine. These derivatives are volatile liquids and can be distilled unchanged under reduced pressure. Alcoholysis of the mixed ethoxy ethylmethyliminoxy arsines give the corresponding higher alkoxy derivatives. I.R. spectra, refractive indices and molecular weights of these derivatives have been measured.

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