Dialkylphosphohate derivatives of arsenic(III)

Nagar, P. N. ; Srivastava, G. ; Mehrotra, R. C. (1982) Dialkylphosphohate derivatives of arsenic(III) Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 12 (6). pp. 749-759. ISSN 1553-3174

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Related URL: http://dx.doi.org/10.1080/00945718208082692


Reactions of dialkylphosphonates with 2-chloro-1,3,2-diox-arsolanes and -arsenanes in the presence of triethylamine yield 2-dialkylphosphonato-1,3,2-diox-arsolanes and -arsenanes, OGO-AsP(O)(OR)2, which are soluble in common organic solvents and are highly susceptible to hydrolysis. The new compounds are characterized by elemental analysis, IR, 1H NMR, and molecular weight measurements.

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