Synthesis of 2,2'-Oxybis (1, 3, 2-dioxarsolanes) and related compounds

Anand, K. L. ; Srivastava, G. ; Mehrotra, R. C. (1977) Synthesis of 2,2'-Oxybis (1, 3, 2-dioxarsolanes) and related compounds Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 7 (5). pp. 421-432. ISSN 1553-3174

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Reactions of arsenic trioxide with various 1,2-diols (viz., ethane-1, 2-diol; propane-1, 2-diol; butane-2, 3-diol and 2, 3-dimethylbutane-2, 3-diol), 1, 3-diols (viz., propane-1, 3-diol; butane-1, 3-diol and 2-methyl-pentane-2, 4-diol) and pentane-1, 5-diol in 1:2 and 1:3 molar ratios give the corresponding 2, 2'-oxybis (1, 3, 2-diox-arsolanes and -arsinanes) and 2,2'-alkylenedioxybis-(1, 3, 2-diox-arsolanes and -arsinanes) respectively as volatile liquids which are susceptible to hydrolysis. 2-Chloro-1, 3, 2-diox-arsolanes and -arsinanes can be synthesized in quantitative yields by reactions of the latter types of derivatives with arsenic trichloride.

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