Govil, S. ; Mehrotra, R. C. (1975) Some double ethoxides of alkaline earth metals with aluminium Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 5 (4). pp. 267-277. ISSN 1553-3174
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Related URL: http://dx.doi.org/10.1080/00945717508057317
Abstract
Double metal ethoxides with the general formula M[Al(OEt)4]2 have been synthesized from the reactions of aluminium ethoxides with bivalent alkaline earth metals (Mg, Ca, Sr or Ba) in ethyl alcohol. All of these are soluble in ethyl alcohol as well as in benzene and some of these can be volatilised under reduced pressure. Alcoholysis reactions with normal and tertiary butyl alcohols gave products of the types M[Al(OBun)4]2 and M[Al(OEt) (OBut)3]2 respectively. Molecular weights and n. m.r. spectra have been reported and discussed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Taylor and Francis Ltd. |
| ID Code: | 30215 |
| Deposited On: | 22 Dec 2010 10:37 |
| Last Modified: | 07 Jun 2011 07:02 |
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