Synthesis and characterization of bimetallic alkoxides of beryllium and aluminum

Aggrawal, M. ; Mehrotra, R. C. (1984) Synthesis and characterization of bimetallic alkoxides of beryllium and aluminum Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 14 (1). pp. 139-150. ISSN 1553-3174

Full text not available from this repository.

Official URL: http://www.informaworld.com/smpp/content~db=all~co...

Related URL: http://dx.doi.org/10.1080/00945718408057518

Abstract

Bimetallic alkoxides of Be and Al with the general formulae Be [Al (OR)4]2 (where R = Me, Et, Prn, Bun, Bu1, Bus and Ami) or Be [Al(OPri) (OR') 3]2 (where R' = But or Amt), have been synthesised by alcoholysis reactions of Be[Al(OPri)4]2. With the exception of Be[Al (OMe)4]2 and Be[Al (OEt)4]2, all these products are volatile under reduced pressure, soluble in common organic solvents and monomeric in refluxing benzene. All these products are highly susceptible to hydrolysis even by atmospheric moisture. The new compounds have been characterized by elemental analysis, ir and pmr spectra.

Item Type:Article
Source:Copyright of this article belongs to Taylor and Francis Ltd.
ID Code:30212
Deposited On:22 Dec 2010 10:38
Last Modified:07 Jun 2011 06:14

Repository Staff Only: item control page