Synthesis of 2-(trimethylsiloxy)-1,3,2-dioxaborolanes and related compounds

Mehrotra, S. K. ; Srivastava, G. ; Mehrotra, R. C. (1974) Synthesis of 2-(trimethylsiloxy)-1,3,2-dioxaborolanes and related compounds Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 4 (1). pp. 27-36. ISSN 1553-3174

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Related URL: http://dx.doi.org/10.1080/00945717408069628

Abstract

Some 2-(trimethylsiloxy)-1,3,2-dioxaborolanes and borinanes have been synthesized by cleavage of corresponding trialkyltin or germanium derivatives with trimethylchlorosilane. Bis(4,4,6-trimethyl-1,3,2-dioxaborinane-2-oxy)-dimethylsiloxane was also synthesized by the reaction of triphenyltin derivative with dimethyldichlorosilane in (2:1) molar ratio. Some physical measurements, e.g., molecular weights, infra-red and p.m.r. spectra have been recorded.

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