Chemistry of alkoxo complexes, part II. synthesis and characterization of some mono(chelato)mono(alkoxo)nickel(II) complexes

Baranwal, B. P. ; Mehrotra, Ram C. (1977) Chemistry of alkoxo complexes, part II. synthesis and characterization of some mono(chelato)mono(alkoxo)nickel(II) complexes Transition Metal Chemistry, 3 (1). pp. 220-224. ISSN 0340-4285

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Official URL: http://www.springerlink.com/content/u3522hlt634l64...

Related URL: http://dx.doi.org/10.1007/BF01393551

Abstract

Mono(chelato)mono(alkoxo)nickel(II) complexes of the general formula, Ni(OR)(βdk) (R = Me, i-Pr and βdk = acac, bazac, dbzm and tta) have been synthesized by the reactions of nickel alkoxides, Ni(OR)2(R = Me and i-Pr) with acetylacetone (Hacac), benzoylacetone (Hbzac), dibenzoylmethane (Hdbzm) and 2-thienoyltrifluoroacetone (Htta). These derivatives interchange their alkoxy groups quantitatively with other alcohols. Molecular weight, i.r., electron spin resonance, electronic reflectance spectral and magnetic susceptibility studies have been carried out.

Item Type:Article
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Deposited On:22 Dec 2010 16:10
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