Preparation and properties of some organotin compounds: II. β-diketone complexes of alkyltin compounds

Mehrotra, R. C. ; Gupta, V. D. (1965) Preparation and properties of some organotin compounds: II. β-diketone complexes of alkyltin compounds Journal of Organometallic Chemistry, 4 (3). pp. 237-240. ISSN 0022-328X

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Official URL: http://dx.doi.org/10.1016/S0022-328X(00)94164-0

Related URL: http://dx.doi.org/10.1016/S0022-328X(00)94164-0

Abstract

A number of distillable complexes have been obtained from reaction between dibutyltin diethoxide and acetylacetone, methyl acetoacetate or ethyl acetoacetate. The products are monomeric, which indicates possible octahedral configuration. The triethyltin acetylacetonate has also been shown to be monomeric in benzene, and may contain a five-coordinated tin atom. Trimethyltin methoxide also is only slightly associated in benzene or either.

Item Type:Article
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ID Code:30180
Deposited On:22 Dec 2010 10:45
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