Mixed aldimine derivatives of aluminium

Agrawal, M. ; Tandon, J. P. ; Mehrotra, R. C. (1979) Mixed aldimine derivatives of aluminium Journal of Inorganic and Nuclear Chemistry, 41 (10). pp. 1405-1407. ISSN 0022-1902

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Official URL: http://dx.doi.org/10.1016/0022-1902(79)80201-8

Related URL: http://dx.doi.org/10.1016/0022-1902(79)80201-8


1:1:1 Molar reactions of Al(OPri)3 with monofunctional bidentate and bifunctional tridentate Schiff bases have yielded mixed Schiff base derivatives of the type (S'B')Al(SB) (where S'B'2- and SB- are the anions of bifunctional tridentate and monofunctional bidentate Schiff bases respectively). If these complexes are monomeric, the central aluminium atom will be pentacoordinated, and this is suggested by the addition reaction with pyridine. Structures based on IR and NMR spectra have been suggested.

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