Puri, D. M. ; Mehrotra, R. C. (1961) Derivatives of titanium with compounds having bidentate ligands: I. reactions of titanium tetrachloride Journal of the Less Common Metals, 3 (3). pp. 247-252. ISSN 0022-5088
Full text not available from this repository.
Official URL: http://dx.doi.org/10.1016/0022-5088(61)90067-4
Related URL: http://dx.doi.org/10.1016/0022-5088(61)90067-4
Abstract
The reaction between titanium tetrachloride and acetyl acetone, ethyl acetoacetate, methyl acetoacetate and methyl salicylate has been studied and the compounds TiCl2(acac)2, TiCl2(methyl acetoacetate)2, TiCl2(ethyl acetoacetate)2 and TiCl2(methyl salicylate)2 have been isolated. The compound, [Zr(acac)3]Cl, has also been prepared by the reaction between zirconium tetrachloride and acetyl acetone. By molecular weight measurements these compounds have been shown to be monomeric in nature rather than trimeric, as had been assumed by earlier workers.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 30170 |
| Deposited On: | 22 Dec 2010 10:47 |
| Last Modified: | 08 Jun 2011 05:21 |
Repository Staff Only: item control page
