Organic derivatives of tin: VI. reactions of butyltin triisopropoxide with alkanolamines

Gaur, D. P. ; Srivastava, G. ; Mehrotra, R. C. (1974) Organic derivatives of tin: VI. reactions of butyltin triisopropoxide with alkanolamines Journal of Organometallic Chemistry, 66 (2). pp. 195-204. ISSN 0022-328X

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Official URL: http://dx.doi.org/10.1016/S0022-328X(00)91270-1

Related URL: http://dx.doi.org/10.1016/S0022-328X(00)91270-1

Abstract

Butyltin triisopropoxide, BuSn(OPr-i)₃, reacts with various alkanolamines, viz. HOCH₂ CH₂NH₂, HOCH₂CH₂CH₂NH₂, HOCH₂CH₂NHMe, (HOCH₂CH₂)₂NH and (HOCH₂CH₂)₃N in different molar ratios to yield cyclic derivatives. Identical products are obtained by the reactions of BuSnO 3/2 with HOCH₂CH₂NHMe and (HOCH₂CH₂)₃N. Alcoholysis reactions of BuSn(OPr-i)₃ with HOXNMe₂ (X = CH₂CH₂ and CHMeCH₂) yield distillable BuSn(OPr-i)_3-n (OXNMe₂)_n (n = 1, 2 and 3) according to molar ratios of the reactants. Molecular weights and IR spectra are reported.

Item Type:	Article
Source:	Copyright of this article belongs to Elsevier Science.
ID Code:	30168
Deposited On:	22 Dec 2010 10:47
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