Goel, A. B. ; Ashby, E. C. ; Mehrotra, R. C. (1982) Characterization of the products of the reactions of magnesium hydride with isopropylborate and aluminum isopropoxide in tetrahydrofuran Inorganica Chimica Acta, 62 . pp. 161-166. ISSN 0020-1693
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Official URL: http://dx.doi.org/10.1016/S0020-1693(00)88496-0
Related URL: http://dx.doi.org/10.1016/S0020-1693(00)88496-0
Abstract
Exchange of hydrogen with isopropoxy groups in the reactions of magnesium hydride with isopropylborate and aluminum isopropoxide in THF has been demonstrated and the formation of mixed 'isopropoxy-hydride' complexes of boron and aluminum magnesium have been characterized by infrared, nmr, X-ray powder diffraction and elemental analysis. The selectivity of mixed 'alkoxyhydride' complexes as reducing agents toward cyclic and bicyclic ketones has been investigated.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 30163 |
| Deposited On: | 22 Dec 2010 10:48 |
| Last Modified: | 07 Jun 2011 06:23 |
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