Thiolysis of alkyltin alkoxides and oxides

Sukhani, D. ; Gupta, V. D. ; Mehrotra, R. C. (1967) Thiolysis of alkyltin alkoxides and oxides Journal of Organometallic Chemistry, 7 (1). pp. 85-90. ISSN 0022-328X

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Dibutyltin diethoxide was found to interchange its ethoxy groups readily with thiols forming Bu2Sn(SR)2. These thiolates can also be synthesized by refluxing the crude Bu2SnO with thiols in the presence of benzene. Molecular weight determinations showed them monomeric. Some of these higher homologues can be prepared by displacement reactions with higher thiols. The reaction of dipropanethiodibutylstannane with ethanol is very slow even in the presence of catalyst.

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