Studies in aluminium soaps- II mono- and di-soaps of aluminium

Pande, K. C. ; Mehrotra, R. C. (1957) Studies in aluminium soaps- II mono- and di-soaps of aluminium Journal of Inorganic and Nuclear Chemistry, 4 (2). pp. 128-130. ISSN 0022-1902

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Official URL: http://dx.doi.org/10.1016/0022-1902(57)80094-3

Related URL: http://dx.doi.org/10.1016/0022-1902(57)80094-3

Abstract

Strong evidence has been adduced for the existence of mono- and di-soaps of aluminium by preparative methods. Mono-and di-isopropoxy laurates and stearates of aluminium have been prepared by metathetic reactions between aluminium isopropoxide and the calculated amount of the corresponding fatty acid. The isopropoxy-laurates, on treatment with acetyl chloride, have been shown to yield mono- and di-chloride laurates. All these soaps give solutions of low viscosity in benzene. When the di-isopropoxy stearate was treated with acetic anhydride, the isopropoxy as well as the stearate groups were replaced by acetoxy radicals and thus no pure acetoxy-soap could be isolated.

Item Type:Article
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ID Code:30143
Deposited On:22 Dec 2010 10:52
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