Mehrotra, R. C. ; Gupta, V. D. ; Sukhani, D. (1967) Butylgermanethiolates Journal of Organometallic Chemistry, 9 (2). pp. 263-269. ISSN 0022-328X

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Official URL: http://dx.doi.org/10.1016/S0022-328X(00)83728-6

Related URL: http://dx.doi.org/10.1016/S0022-328X(00)83728-6


A number of new, volatile butylgermanethiolates Bu2Ge(SR)2 and Bu3Ge(SR) (R = C2H5, C3H7, iso-C3H7, C4H9, iso-C4H9, tert-C4H9, n-C12H25, CH2C6H5 and C6H5) have been synthesized by the reaction of the corresponding chlorogermane with thiol in the presence of a proton acceptor. The action of thiol on di- and tributylgermanium oxides could be pushed to completion in the presence of catalyst. A few typical displacement reactions of these derivatives with thiol as well as ethanol have been studied. Infrared spectra of these butylgermanethiolates have been examined.

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