Some new salicyldeneimine complexes of diorganotin(IV)

Tiwari, Rashmi ; Srivastava, G. ; Mehrotra, R. C. ; Crowe, A. J. (1986) Some new salicyldeneimine complexes of diorganotin(IV) Inorganica Chimica Acta, 111 (2). pp. 167-170. ISSN 0020-1693

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Sixteen new dialkyltin derivatives of the type R2S nOC6H4C(R')=NR"O (R = Me, Et, Bu and Ph; R' = H and Me and R" = ---CH2CH2--- and ---CH2CH2CH2---) have been synthesised by the reactions of dialkyltin diisopropoxides with the corresponding Schiff bases in refluxing benzene, followed by removal of isopropanol azeotropically. Pentacoordination of tin in these compounds has been proposed on the basis of elemental analyses, molecular weight determinations, IR, PMR and Mossbauer spectral studies.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:30132
Deposited On:22 Dec 2010 10:54
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