A study of the tetra-alkylthiostannanes, Sn(SR)4

Mehrotra, R. C. ; Gupta, V. D. ; Sukhani, D. (1967) A study of the tetra-alkylthiostannanes, Sn(SR)4 Journal of Inorganic and Nuclear Chemistry, 29 (7). pp. 1577-1580. ISSN 0022-1902

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Official URL: http://dx.doi.org/10.1016/0022-1902(67)80198-2

Related URL: http://dx.doi.org/10.1016/0022-1902(67)80198-2


The synthesis of tetra-alkylthiostannanes, Sn(SR)4, (where R = C2H5, n-C2H7, iso-C2H7, n-C4H9, iso-C4H9 tert-C4H9, n-CP12H25, C6H5 and C6H5 · CH2) through an alternative convenient route employing ammonia as a proton acceptor is described. Stannic isopropoxide also exchanges its isopropoxy groups with thiols. Thiolysis reactions of Sn(SEt)4 and Sn(SPr)4 with higher thiols have been investigated for the first time.

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Deposited On:22 Dec 2010 10:56
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