Dubey, R. K. ; Singh, A. ; Mehrotra, R. C. (1987) Synthesis and characterization of copper(II) bis(dizirconium-ennea-alkoxides) Polyhedron, 6 (3). pp. 427-433. ISSN 0277-5387
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Official URL: http://dx.doi.org/10.1016/S0277-5387(00)81003-7
Related URL: http://dx.doi.org/10.1016/S0277-5387(00)81003-7
Abstract
Copper(II) bis(dizirconium-ennea-isopropoxide), [Cu{Zr2(OPri)9}2], has been synthesized by the interaction of CuCl2 with K{Zr2OPri9} in a 1:2 molar ratio. The compound undergoes exchange reactions with alcohols of varying steric bulk to yield products of the composition, [Cu{Zr2(OR)9}2] (where R = Me, Et, Prn, Bun, Bui and Bus); [Cu{Zr2(OPri)6(OEt)3} 2]; [Cu{Zr2(OPri)6(OBus) 3}2]; [Cu{Zr2(OPri)3 (OBus6}2];[Cu{Zr2OPri)7 (OBut)2}2]; [Cu{Zr2(OPri)3(OBut)6}2]; and [Cu{Zr2(OPri)4(OAmt) 5}2]. These derivatives have been characterized by IR, electronic and ESR studies as well as by magnetic susceptibility and molecular weight determinations.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 30113 |
| Deposited On: | 23 Dec 2010 03:11 |
| Last Modified: | 07 Jun 2011 05:11 |
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