Saxena, U. B. ; Rai, A. K. ; Mathur, V. K. ; Mehrotra, R. C. ; Radford, D. (1970) Reactions of zirconium isopropoxide with β-diketones and β-keto-esters Journal of the Chemical Society A . pp. 904-907. ISSN 0022-4944
Full text not available from this repository.
Official URL: http://www.rsc.org/publishing/journals/article.asp...
Related URL: http://dx.doi.org/10.1039/J19700000904
Abstract
The reactions of zirconium isopropoxide with acetylacetone, benzoylacetone, dibenzoylmethane, and ethyl benzoylacetate have been studied and a number of new derivatives of the type M(OPri)4-xLx(where M = Zr, L = acetylacetone, benzoylacetone, dibenzoylmethane, or ethyl benzoylacetate, x= 1-4) have been isolated. These derivatives interchange their isopropoxy- for t-butoxy-groups when heated under reflux with t-butyl alcohol. Structures of these derivatives have been discussed on the basis of analysis, molecular weight, and i.r. spectral studies.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 30098 |
| Deposited On: | 23 Dec 2010 03:14 |
| Last Modified: | 08 Jun 2011 04:42 |
Repository Staff Only: item control page
