Reactions of oximes with zirconium isopropoxide

Singh, A. ; Rai, A. K. ; Mehrotra, R. C. (1973) Reactions of oximes with zirconium isopropoxide Inorganica Chimica Acta, 7 . pp. 450-452. ISSN 0020-1693

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Zirconium isopropoxide isopropanolate reacts with various oximes in refluxing benzene to give complexes of the formula, Zr(OPr)i4-x (ON = CR1R2) x (x = 1-4; R1 = Me, Et; R2 = Me, Et, Prn, Pri, Ph; R1 = R2 = (CH2)5. Ebullioscopic molecular weight measurements in benzene show that some of these derivatives are polymeric in nature. I.r. spectra have been recorded and some probable assignment have been made.

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