Derivatives of aluminium with some α-hydroxy carboxylic acids

Rai, A. K. ; Mehrotra, R. K. ; Mehrotra, R. C. (1963) Derivatives of aluminium with some α-hydroxy carboxylic acids Journal fur Praktische Chemie, 20 (1-2). pp. 105-112. ISSN 1436-9966

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/prac.19...

Related URL: http://dx.doi.org/10.1002/prac.19630200113

Abstract

The reactions of aluminium isopropoxide and aluminium chloride with salicylic, mandelic and lactic acids in different stoichiometric ratios have been studied under absolutely anhydrous conditions. Mandelic and lactic acids were found to give tri-derivatives, whereas the salicylic acid gave only di-salicylate when the ratios of alkoxide and the acid was 1:3 (or slightly higher) or an equimolecular mixture of di-and tri-salicylate when the ratio was increased to 1:3.4 (or 3.4).

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Deposited On:23 Dec 2010 03:17
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