Gaur, D. P. ; Srivastava, G. ; Mehrotra, R. C. (1973) Organic derivatives of tin IV. Reactions of dialkyltin dialkoxides with alkanolamines Journal of Organometallic Chemistry, 63 . pp. 213-219. ISSN 0022-328X
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00223...
Related URL: http://dx.doi.org/10.1016/S0022-328X(73)80033-6
Abstract
Dibutyltin diethoxide, Bu2Sn(OEt)2, reacts with various alkanolamines, HOXNH2, (X=CH2CH2CH2, CH(Me)CH2), HOXNR2 (X=CH(Me)CH2 and R=Me; X=CH2CH2CH2 and R=Et) in 1/1 and 1/2 molar ratios to yield distillable dibutyl(ethoxy)tin aminoalkoxides, Bu2Sn(OEt)(OXNR2) and dibutyltin bis(aminoalkoxides) Bu2Sn(OXNR2)2, respectively. For reactions of R2Sn(OR')2 (R=Et, n-Pr and R'=Et; R=Et and R'=t-Bu) with HOXNH2 (X=CH2CH2, CH2CH2CH2 and CH(Me)CH2), cyclic compounds of the type R2Sn(OXNH) are obtained. Molecular weights and IR spectra of the new products are reported and discussed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 30069 |
| Deposited On: | 23 Dec 2010 03:20 |
| Last Modified: | 08 Jun 2011 04:28 |
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