Sogani, Sanjeev ; Singh, Anirudh ; Mehrotra, Ram C. (1995) Synthesis and characterization of nonaisopropoxodistannato complexes of magnesium(II), barium(II), zinc(II) and cadmium(II) Polyhedron, 14 (5). pp. 621-627. ISSN 0277-5387
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/027753...
Related URL: http://dx.doi.org/10.1016/0277-5387(94)00285-M
Abstract
Novel heterobimetallic isopropoxides of the types [MSn2Cl(OPri)9]2(A) and [MSn4(OPri)18](B) (M = Mg, Zn or Cd) have been synthesized by the reactions of MCl2 (M = Mg, Zn or Cd) with KSn2 (OPri)9 in 1:1 and 1:2 molar ratios respectively. Derivatives [MSn2(OPri)10]2(C) (M = Cd) and [MAlSn2(OPri)13](D), where M = Zn, Cd or Mg have also been prepared by the equimolar reactions of A with KOPri or KAl(OPri)4 respectively. Further, the derivatives, [BaSn2(OPri)10] 2and [BaSn4(OPri)18] have been obtained by the reactions of barium with isopropyl alcohol in the presence of required molar ratios of Sn(OPri) 4 · PriOH.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 30059 |
| Deposited On: | 23 Dec 2010 03:25 |
| Last Modified: | 07 Jun 2011 04:39 |
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