Synthesis of silyloxides of gadolinium and erbium

Batwara, J. M. ; Mehrotra, R. C. (1970) Synthesis of silyloxides of gadolinium and erbium Journal of Inorganic and Nuclear Chemistry, 32 (2). pp. 411-415. ISSN 0022-1902

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002219...

Related URL: http://dx.doi.org/10.1016/0022-1902(70)80248-2

Abstract

Lanthanon compounds containing M---O---Si bonds have been prepared by the reactions between lanthanon isopropoxides and trimethylsilylacetate in different molar ratios in refluxing cyclohexane (M=Gd or Er). The mono- or di-isopropoxy silyloxides interchange their isopropoxy groups with tertiary butoxy groups on alcoholysis. Molecular weights and i.r. spectra studies indicate that they are polymeric.

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ID Code:30045
Deposited On:23 Dec 2010 03:39
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