Synthesis and characterization of some alkoxide derivatives of nickel(II)

Baranwal, B. P. ; Mehrotra, R. C. (1980) Synthesis and characterization of some alkoxide derivatives of nickel(II) Australian Journal of Chemistry, 33 (1). pp. 37-43. ISSN 0004-9425

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Official URL: http://www.publish.csiro.au/paper/CH9800037.htm

Related URL: http://dx.doi.org/10.1071/CH9800037

Abstract

A number of alkoxides and chloride alkoxides of nickel(II) of the types Ni(OR)2, Ni(OR)Cl and Ni(OR)Cl,ROH have been synthesized from the reactions of anhydrous nickel(II) chloride with lithium or sodium alkoxides in appropriate molar ratios. These derivatives have been characterized by element analysis, infrared, electronic reflectance and electron spin resonance spectra in addition to magnetic susceptibility measurements. Alcohol interchange reactions in these alkoxide derivatives have been studied in detail.

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